Fatigue and Tribological Properties of Plastics and Elastomers – Third Edition

Fatigue and Tribological Properties of Plastics and Elastomers – Third Edition
اسم المؤلف
Laurence W. McKeen
التاريخ
8 نوفمبر 2023
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366
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Fatigue and Tribological Properties of Plastics and Elastomers – Third Edition
Laurence W. McKeen
Table of contents

  1. Introduction to fatigue
  2. Introduction to the Tribology of Plastics and Elastomers
  3. Introduction to Plastics and Polymers
  4. Styrenics
  5. Polyethers
  6. Polyesters
  7. Polyimides
  8. Polyamides
  9. Polyolefins And Acrylics
  10. Thermoplastic Elastomers
  11. Fluoropolymers
  12. High Temperature Plastics
    Appendices
    Abbreviations
    Tradenames
    Conversion Factors
    Subject Index
    A
    ABS. See Acrylonitrile-butadiene-styrene
    (ABS)
    Acetal copolymer. See Polyoxymethylene
    copolymer (POM-Co)
    Acetal polymers, 87
    Acetals-polyoxymethylene
    homopolymer, 87
    chemical structure of, 87
    for DuPont Delrin® 500 acetal resin, 93
    DuPont Delrin® acetal resins, 90
    higher-stiffness, 89
    low-friction and low-wear, 89
    DuPont Delrin® 100, 500, and 900, 92
    for DuPont Delrin® 500 and 500CL
    medium-viscosity POM
    resins, 92
    DuPont Delrin® POM Plastics, 94
    dynamic coefficient of DuPont Delrin®
    friction, 94
    fatigue crack propagation vs. stress
    intensity factor
    molecular weights of generic unfilled
    POM, 91
    fatigue data, 87
    flexural stress amplitude vs. cycles to
    failure
    for DuPont Delrin® 100, 500, and
    900, 91
    general-purpose DuPont Delrin® acetal
    resins, 88
    RTP Company RTP 800 TFE 20
    DEL—POM Homopolymer, 94
    stress amplitude vs. cycles to failure
    for DuPont Delrin® 500, 90
    Teflon® PTFE levels in DuPont
    Delrin®, 93
    toughened DuPont Delrin® acetal
    resins, 88
    tribology data, 87
    UV-stabilized, 90
    Acrylic polymers, 261
    Acrylics, 261
    Acrylonitrile-butadiene-styrene (ABS),
    68, 171
    copolymer, 56
    fatigue data, 72
    flexural stress amplitude vs. cycles to
    failure, 71
    grades available, 72
    polymerization, 72
    styrene acrylonitrile (SAN)
    chemical structure of, 70
    tensile stress amplitude vs. cycles to
    failure
    for SABIC Innovative Plastics
    Cycolac® BDT5510 ABS, 74
    for SABIC Innovative Plastics
    Cycolac® BDT6500—ABS, 74
    for SABIC Innovative Plastics
    Cycolac® CGA—ABS, 74
    for SABIC Innovative Plastics
    Cycolac® CGF20, 75
    for SABIC Innovative Plastics
    Cycolac® CTR52, 75
    for SABIC Innovative Plastics
    Cycolac® EX39, 75
    for SABIC Innovative Plastics
    Cycolac® EX58, 76
    for SABIC Innovative Plastics
    Cycolac® EX75, 76
    for SABIC Innovative Plastics
    Cycolac® G-100 ABS, 73
    ultrasonic fatigue testing, 73
    Acrylonitrile monomers, 68
    American Society for Testing and
    Materials (ASTM), 4
    Amorphous nylon, 220
    fatigue crack propagation rate vs. stress
    intensity factor
    Evonik Industries Trogamid® T5000,
    253
    fatigue data, 223
    flexural stress amplitude vs. cycles to
    failure
    EMS-Grivory Grilamid® amorphous
    6-3-T polyamide plastics, 254
    flexural stress amplitude vs. cycles to
    failure of
    Evonik Industries Trogamid® T5000,
    255
    monomers used, to Grilamid® TR55, 253
    PACM 12 semicrystalline polyamide
    chemical structure of, 253
    6-3-T amorphous nylon
    chemical structure of, 253
    tensile fatigue limit
    Evonik Industries Trogamid® T5000,
    254
    Amorphous plastics, 54
    Amorphous polymers, 220
    Amorphous regions, 291
    Aromatic polyamide fiber, 43
    ASA polymers, 65
    ASTM D1894-08 Standard Test
    Method, 34
    Atactic polypropene, 50
    B
    Ball-and-stick three-dimensional
    representation, of
    perfluoroalkoxy (PFA), 307
    BASF Elastollan 500 Grades PolyetherPolyurethane Thermoplastic
    Elastomers, 282
    Block techniques, create long-chain
    molecules, 279
    BPADA-based PIs, 197
    C
    Carbon black, 62
    Carbon fibers, 43
    CAS Number, 330
    Celazole PBI, 337
    Chemical Abstract Service (CAS), 62
    Chemours Teflon® FEP, 299
    Chlorinated polyvinyl chloride
    (CPVC), 268
    Coefficient of friction (COF), 27
    COOH acid group, 199
    Copolymers, 46
    high-impact polystyrene (HIPS), 46
    linear/branched/cross-linked
    polymers, 47
    polystyrene, fatigue crack
    propagation, 47
    Cross-linked polyethylene, 262
    peroxide/engel method (PEX-a), 262
    radiation/electron-beam method
    (PEX-c), 263
    silane method (PEX-b), 262
    D
    Degree of polymerization, 53
    Degree of unsaturation (DoU), 48
    DeMattia Flex test, 11
    Design against fatigue, 24–25
    Dipole moment, 47
    Dry as molded (DAM), 199
    DuPont Company, 182, 311
    DuPont Hytrel® polyester TPEs, 281
    DuPont Rynite®, 149
    DuPont’s method, 87
    DuPont Teijin Films™ Mylar® and
    Melinex®, 149
    E
    Eccentric machines, 5
    ECTFE-based plastics, 294
    Elastomeric alloy-thermoplastic
    vulcanizates (EA-TPVs), 289346 Subject Index
    Elastomers, 55, 289
    antistatic agents, 60
    carbon black, 62
    catalysts, 58
    combustion modifiers, 57
    component of, 45
    composite materials, several types of, 57
    coupling agents, 62
    fatigue life comparison
    of carbon and glass fiber–reinforced
    polyamide, 58
    fillers, reinforcement, composites, 56
    fire, 57
    flame retardants, 57
    impact modifiers/tougheners, 58
    linkage-based names, 63
    polymer, 62
    lubricants/slip agents/tribology
    additives, 58
    methacrylate–butadiene styrene rubber
    (MBS), 60
    micrograph of orthotropic fiber-glass
    orientation, 57
    micrograph of random fiber-glass
    orientation, 57
    multiple polymer names, for same
    materials, 63
    notched Izod of BASF Ultramid® B-3
    Nylon 6, 59
    optical brighteners, 60
    pigments/extenders/dyes/mica, 61
    plastic compositions, 55
    plasticization by water absorption, 61
    plasticizers, 61
    polymer nomenclature, 62
    release agents/antiblocking agents, 58
    smoke suppressants, 57
    source-based names, 62
    structure-based names, 62
    thermal stabilizers, 62
    titanium dioxide, 61
    tortuous path of permeant molecule, 61
    UV stabilizers, 59
    Electronegativity, 47
    EPDM. See Ethylene-propylene diene
    monomer (EPDM)
    Erosion, 29
    Ethylene–chlorotrifluoroethylene
    copolymer, 293
    Ethylene–propylene diene monomer
    (EPDM), 287
    Ethylene–propylene rubber (EPR), 265
    Expanded polystyrene (EPS), 65
    Extruded polystyrene (XPS), 65
    F
    Fatigue crack propagation (FCP), 264
    Fatigue life, affecting factors, 23
    cyclic stress state, 23
    direction of loading, 24
    environmental conditions, 24
    geometry, 23
    internal defects, size/distribution of, 24
    material type, 23
    residual stresses, 23
    surface quality, 23
    type of fatigue, 23
    Fatigue process, 21
    crack growth/propagation, 21–22
    crack initiation, 21
    failure, 22–23
    Fatigue testing, 4
    ASTM fatigue-related standards, 12
    cantilevered beam eccentric flexural
    fatigue machine, 7
    cantilevered fatigue-testing machine, 9
    ASTM D671, 8
    diagram of, 8
    coupons, 4
    crack growth graph, 22
    cyclic stress–strain curve, 18
    data, understanding, 16
    cyclic stress–strain behavior, 17–18
    monotonic stress–strain behavior,
    16–17
    strain–life behavior, 18–19
    stress–life behavior, 20–21
    DeMattia Flex tester, 12
    DIN fatigue-related standards, 15
    eccentric machine
    flexural oscillation fatigue tests, 7
    for tensile/compressive oscillation, 5
    failure, plastic specimen, 17
    fatigue fracture, surface of, 23
    fatigue resistance, 23
    in compression, 24
    flex life machines, 10–11
    flexural eccentric fatigue machine, 7
    fracture standards, 12
    generic Haigh diagram, 21
    ISO fatigue-related standards, 14
    JIS fatigue-related standards, 15
    method, 10
    MIT Flex Life tester, 11
    polytetrafluoroethylene
    testing frequency on fatigue
    properties, 11
    PTFE samples, measured temperature
    of, 10
    Ross Flex tester, 11
    servohydraulic/electrohydraulic/pulsator
    fatigue-testing machines, 8–9
    servohydraulic fatigue-testing machine
    with environmental chamber, 9
    flexural test rig, 9
    sheet fatigue-testing specimens,
    illustration of, 4
    short-term S–N data, 25
    strain–life curve
    effect of mean stress, 20
    modeled, 19
    strain–life plot, 19
    stress–strain behavior, 18
    stress/strain, cyclic nature of, 6
    tensile eccentric fatigue machine, 5–6
    photograph of, 6
    test piece geometry on fatigue
    resistance, 24
    typical molded rod fatiguetesting
    specimens, 5
    typical monotonic stress–strain
    curve, 16
    typical stress–life curves, 20
    ultrasonic fatigue, 9
    FCP. See Fatigue crack propagation (FCP)
    FEP. See Fluorinated ethylene propylene
    (FEP)
    Flexible PVC compounds, 269
    Fluorescent brightening agents (FBAs), 60
    Fluorescent whitening agents (FWAs), 60
    Fluorinated ethylene propylene (FEP),
    296, 299
    ball-and-stick three-dimensional
    representation, 305
    chemical structure of, 305
    Chemours Teflon® FEP
    PV and wear factors, 306
    coefficient of friction vs. load
    Chemours Teflon® FEP 100 resin, 306
    dynamic coefficient of friction vs.
    sliding speed
    Chemours Teflon® FEP, 306
    fatigue data, 300
    hexafluoropropylene (HFP), 299
    MIT Fold Endurance of Chemours
    Teflon® FEP Resins, 305
    three-dimensional representation
    of, 305
    tribology data, 300
    Fluorine, 303
    Fluoroplastics, 291
    melting point ranges of, 292
    Fluoropolymers, 291
    amorphous regions, 291
    PTFE molecule, 291
    Frictional force, 27–28
    characterizing wear, 31
    environmental conditions, 34
    PV limit, 33–34
    wear factor, 32
    wear rate, 32
    coefficient of friction
    sliding speed and pressure, 28
    temperature for DuPont Vespel
    SP-21, 28
    DuPont Vespel® SP-21
    dependence of wear factor
    different hardness, 33
    roughness levels, 33
    temperature dependence of wear
    factor, 32
    effect of moisture content of gas, 34
    illustration of, 27
    lubrication, 28–29
    between block and plate, 28
    DuPont Vespel® SP-21, 29
    microscopic scale, illustration of, 27
    wear classified by mechanism, 31
    Fully hydrodynamic, 29Subject Index 347
    G
    Geometric isomers, 50
    Glass fibers, 43
    Grilamid® TR55, 220
    H
    Hexafluoropropylene (HFP), 299
    High-density polyethylene (HDPE), 261
    High-performance liquid chromatographic
    (HPLC) columns, 317
    Hindered amine light stabilizer
    (HALS), 59
    Homopolymers, 263, 291
    HVAC equipment, 111
    I
    Imide polymer blends, 193
    DuPont Engineering Polymers Vespel®
    TP-8000 series
    flexural stress amplitude vs. cycles to
    failure, 195
    thermoplastic polyimide DuPont Vespel®
    TP-8000 series
    chemical structure of, 195
    tribological properties
    Several DuPont Engineering Plastics
    Vespel® TP Series Thermoplastic
    Polyimide Plastics Suzuki Thrust
    Wear Test Results, 196
    Several DuPont Engineering Plastics
    Vespel® TP Series TPI Plastics
    Suzuki Thrust Wear Test, 196
    Imide-type polymer, 171
    Impact copolymers, 264
    Impact wear processes, 30
    Inorganic screeners, 60
    Instrument panels (IPs), 82
    Inversions, 311
    Isomers, 49
    atactic, 50
    cis- and trans, 50
    geometric, 50
    head-to-tail isomers, 50
    isotactic, 50
    isotactic polypropene
    3D ball-and-stick structure of, 50
    structure of, 50
    stereoisomers—syndiotactic, 50
    structural, 49
    syndiotactic polypropene, structure of, 51
    Isophorone bisphenol
    chemical structure of, 126
    Isophorone diisocyanate (IPDI), 280
    Isophthalic acid (IPA), 223
    L
    LCPs. See Liquid crystalline polymers
    (LCPs)
    Lifed part, 25
    Linear low-density polyethylene
    (LLDPE), 261
    Linkage-based names, 63
    Liquid crystal display (LCD), 319
    Liquid crystalline polymers (LCPs), 156
    Celanese Vectra® LCP Grades
    coefficients of friction, 159
    Celanese Vectra® LCP resins
    friction, dynamic coefficient of, 158
    wear volumes, 158
    chemical structures of
    Celanese Vectra® A950, 157
    monomers, 156
    fatigue data, 157
    flexural stress amplitude vs. cycles to
    failure
    Celanese Vectra® fiber-reinforced
    LCP plastics, 157
    Celanese Zenite® 6130 BK010, 158
    tribology data, 157
    Longitudinal stress, 3
    Lubrication, 28
    M
    Medium-density polyethylene
    (MDPE), 261
    Methacrylate acrylonitrile butadiene
    styrene (MABS) copolymer, 78
    4,4′-Methylenediphenyl diisocyanate
    (MDI), 280
    Mica, 61
    M.I.T. Tester, 10
    Monomers, 46
    Multiphase polymer blends, 56
    N
    Nitrile groups, 70
    Nylon 6 (PA6), 200
    characteristics, 201
    chemical structure, 200
    coefficient of friction vs. load
    Toray Resin Company Amilan™
    CM1021, 205
    fatigue data, 201
    flexural stress amplitude vs. cycles to
    failure
    BASF Ultramid® B 3WG6, 204
    EMS-Grivory Grilon® PV-5H, 202
    SABIC Innovative Plastics
    Thermocomp® PF006, 203
    Toray Resin Company Amilan™
    CM1011G-45, 203
    Toray Resin Company Amilan™ PA6
    plastics, 202
    frictional coefficients as load and
    lubrication conditions
    Toray Resin Company Amilan™
    CM1017 PA6 plastics, 206
    load dependence of amount of wear
    Toray Resin Company Amilan™
    PA 6, 207
    load dependence of frictional coefficient
    Toray Resin Company Amilan™
    PA 6, 206
    moisture content Influence on flexural
    fatigue performance
    BASF Capron® 8233G HS, 204
    resistance to tensile–tensile fatigue
    BASF Capron® 8233G HS, 205
    stress amplitude vs. cycles to failure
    BASF Ultramid® glass fiber, 201
    Toray Resin Company Amilan™ CM1017,
    stress–lifetime curve, 202
    tribological properties
    RTP Company RTP 207A TFE 20
    HS, 207
    RTP Company RTP 207A TFE 13 SI
    2 HS, 207
    RTP Company RTP 299A X 90821,
    208
    RTP Company RTP 299A X 82678
    C, 207
    tribology data, 201
    Nylon 11 (PA11), 201
    chemical structure, 208
    taber abrasion resistance
    of Rilsan® AESNO with
    modifications, 208
    tribology data, 203
    Nylon 12 (PA12), 204
    abrasion vs. sliding distance
    Evonik Industries Vestamid® PA12
    plastics, 209
    dynamic coefficient of friction vs.
    bearing pressure
    Evonik Industries Vestamid® L1901, 210
    dynamic coefficient of friction vs.
    bearing temperature
    Evonik Industries Vestamid® L1901,
    210
    fatigue data, 208
    flexural stress amplitude vs. cycles to
    failure
    EMS-Grivory Grilamid® LV-5H, 209
    taber abrasion of
    Evonik Industries Vestamid®, 211
    tribology data, 208
    Nylon 46 (PA46), 208
    chemical structure, 211
    fatigue cycles to failure vs. stress in
    flexure, 211
    glass fiber–reinforced DSM Stanyl®
    PA46 resins, 212
    fatigue cycles to failure vs. stress in
    tension
    DSM Stanyl® TW300 PA46 resin, 212
    fatigue data, 210
    G456 steel of DSM Stanyl® PA46 resin,
    PV diagram, 214
    stress amplitude vs. cycles to failure
    DSM Engineering Plastics Stanyl®
    TE200F6, 212
    tensile fatigue performance
    ASTM D1044 of DSM Stanyl® PA46
    resin, 213
    of DSM Stanyl® TW341, 213
    DSM Stanyl® TW200F6 and
    TW200B6 PA46 resins, 213
    tribology data, 210348 Subject Index
    Nylon 66 (PA66), 210
    axial stress amplitude vs. cycles to
    failure
    DuPont Engineering Plastics Zytel®
    101, 223
    axial tension/compression stress
    amplitude vs. cycles to failure
    DuPont Engineering Plastics Zytel®
    PA66 plastics, 220
    chemical structure, 214
    coefficient of friction vs. load
    Toray Resin Company Amilan™
    CM3001N, 225
    DuPont Engineering Plastics Zytel® 101,
    Sonntag axial fatigue, 221, 222
    fatigue crack propagation rate vs. stress
    intensity factor, 224
    DuPont Engineering Plastics Zytel®
    122L, 223
    fatigue data, 214
    flexural stress amplitude vs. cycles to
    failure
    BASF Ultramid glass fiber, 218
    DuPont Engineering Plastics Minlon®
    mineral, 216
    DuPont Engineering Plastics Zytel®
    101, 221
    DuPont Engineering Plastics Zytel®
    PA66 plastics, 220
    SABIC Innovative Plastics LNP™
    Lubriloy® FR-40, 215
    SABIC Innovative Plastics LNP™
    Thermocomp™ carbon
    fiber, 217
    SABIC Innovative Plastics LNP™
    Thermocomp™ glass fiber, 217
    SABIC Innovative Plastics LNP™
    Verton® long glass fiber, 219
    PV diagram of unreinforced, standardgrade, 225
    RTP 200 Series, wear resistance data of,
    226, 227
    Sonntag flex fatigue stress vs. cycles to
    failure
    for DuPont Engineering Plastics
    Minlon® 23B1, 222
    stress amplitude vs. cycles to failure
    BASF Ultramid®, 215
    tensile stress amplitude vs. cycles to
    failure
    BASF Ultramid® A3WG7, 219
    tribological properties of
    resins, 234
    RTP Company RTP 200 AR 15 TFE
    15 vs. 1018 C Steel, 233
    RTP Company RTP 200 SI 2 vs. 1018
    C Steel, 228
    RTP Company RTP 200 SI 2 vs. RTP
    200 SI 2, 228
    RTP Company RTP 200 TFE 10 SI 2
    vs. 1018 C Steel, 229
    RTP Company RTP 200 TFE 18 SI 2
    vs. 1018 C Steel, 230
    RTP Company RTP 282 TFE 13 SI 2
    vs. 1018 C Steel, 232
    RTP Company RTP 285 TFE 13 SI 2
    vs. 1018 C Steel, 233
    RTP Company RTP 202 TFE 13 SI 2
    vs. RTP 202 TFE 15, 231
    RTP Company RTP 200 TFE 18 SI 2
    vs. RTP 200 TFE 18 SI 2, 230
    RTP Company RTP 202 TFE 13 SI 2
    vs. RTP 202 TFE 13 SI 2, 231
    RTP Company RTP 282 TFE 13 SI 2
    vs. RTP 282 TFE 13 SI 2, 232
    RTP Company RTP 200 TFE 20 vs.
    1018 C Steel, 229
    RTP Company RTP 202 TFE 15 vs.
    1018 C Steel, 230
    RTP Company RTP 205 TFE 15 vs.
    1018 C Steel, 231
    RTP Company RTP 282 TFE 15 vs.
    1018 C Steel, 232
    RTP Company RTP 200 TFE 5 vs.
    RTP 200 SI 2, 228
    RTP Company RTP 200 TFE 10 vs.
    RTP 200 SI 2, 228
    RTP Company RTP 200 TFE 10 vs.
    RTP 200 TFE 10, 229
    RTP Company RTP 200 TFE 20 vs.
    RTP 200 TFE 20, 229
    RTP Company RTP 202 TFE 15 vs.
    RTP 202 TFE 15, 230
    RTP Company RTP 282 TFE 15 vs.
    RTP 282 TFE 15, 232
    tribology data, 214
    Nylon 610 (PA610), 215
    characteristics, 215
    chemical structure of, 248
    fatigue data, 216
    flexural stress amplitude vs. cycles to
    failure
    SABIC Innovative Plastics PA610
    plastics, 248
    tribological properties of
    RTP Company RTP 299B X 89491 A
    vs. 1018 C Steel, 248
    tribology data, 216
    Nylon 612 (PA612), 216
    axial stress amplitude vs. cycles to
    failure
    DuPont Engineering Polymers Zytel®
    158, 249
    chemical structure of, 248
    fatigue data, 218
    flexural stress amplitude vs. cycles to
    failure
    SABIC Innovative Plastics PA612
    plastics, 249
    taber abrasion of
    Evonik Vestamid® PA 612 Resins, 249
    RTP Company RTP 200D TFE 18 SI
    2 vs. 1018 C Steel, 250
    RTP Company RTP 200D TFE 18
    SI 2 vs. RTP 200D TFE 18 SI
    2, 251
    RTP Company RTP 200D TFE 10 vs.
    1018 C Steel, 250
    RTP Company RTP 200D TFE 20 vs.
    1018 C Steel, 250
    RTP Company RTP 202D TFE 15 vs.
    1018 C Steel, 251
    RTP Company RTP 282D TFE 15 vs.
    1018 C Steel, 251
    RTP Company RTP 285D TFE 15 vs.
    1018 C Steel, 252
    RTP Company RTP 200D TFE 10 vs.
    RTP 200D TFE 10, 250
    RTP Company RTP 200D TFE 20 vs.
    RTP 200D TFE 10, 250
    RTP Company RTP 202D TFE 15 vs.
    RTP 202D TFE 15, 251
    RTP Company RTP 282D TFE 15 vs.
    RTP 282D TFE 15, 252
    RTP Company RTP 285D TFE 15 vs.
    RTP 285D TFE 15, 252
    tribology data, 218
    Nylon 666 or 66/6 (PA 666), 218
    fatigue data, 219
    flexural stress amplitude vs. cycles to
    failure
    EMS-Grivory Grivory® GV-5H, 252
    Nylons
    amino acids, chemical structures of, 200
    diacids, chemical structures of, 200
    diamines, chemical structures of, 199
    generalized reaction, 199
    high-molecular-weight polyamides, 199
    monomers, 199
    O
    Optical brightening agents (OBAs), 60
    P
    PA6. See Nylon 6 (PA6)
    PA11. See Nylon 11 (PA11)
    PA12. See Nylon 12 (PA12)
    PA46. See Nylon 46 (PA46)
    PA66. See Nylon 66 (PA66)
    PA610. See Nylon 610 (PA610)
    PA612. See Nylon 612 (PA612)
    PAEK. See Polyaryl ether ketones (PAEK)
    PAIs. See Polyamide-imides (PAIs)
    PBI. See Polybenzimidazole (PBI)
    PBT. See Polybutylene terephthalate
    (PBT)
    PC polyester. See Polycarbonate (PC)
    polyester
    PCTFE. See Polychlorotrifluoroethylene
    (PCTFE)
    PEI. See Polyetherimide (PEI)
    Perfluoroalkoxy (PFA), 300
    ball-and-stick three-dimensional
    representation, 307
    chemical structure, 307
    comonomers, 307
    dynamic coefficient of friction vs.
    temperatureSubject Index 349
    of DuPont Engineering Polymers
    Vespel® CR-6100, 308
    fatigue data, 302
    flex life properties
    Solvay Solexis PFA Products, 309
    MIT Flex Life Asahi Glass Fluon® PFA
    resins, 308
    MIT flex life vs. melt flow index, 308
    three-dimensional representation of, 307
    tribology data, 303
    tribology properties
    DuPont Engineering Polymers
    Vespel® CR-6100, 309
    wear factor vs. temperature
    of DuPont Engineering Polymers
    Vespel® CR-6100, 309
    Perfluoropolyether (PFPE) synthetic oil,
    41, 58
    PES. See Polyethersulfone (PES)
    PET. See Polyethylene terephthalate (PET)
    PFA. See Perfluoroalkoxy (PFA)
    Phenolic antioxidants, 60
    Phosphite antioxidants, 60
    PI. See Polyimide (PI)
    Pin-on-disk tribometer, 36
    Plastic, component of, 45
    Polarity, 47
    dipole moments, 48
    Polyacrylics, 270
    fatigue crack propagation rate vs.
    temperature, 277
    cycle frequency, 276
    molecular weight, 276
    fatigue data, 271
    flexural stress amplitude vs. cycles to
    failure
    Lucite International Inc. Diakon™
    CMG302, 274
    PMMA, structure of, 274
    stress amplitude vs. cycles to failure
    Lucite International Inc. Diakon™
    CMG302, 275
    tension/compression stress amplitude vs.
    cycles to failure, 275
    Polyamide copolymers, 220
    Polyamide-imides (PAIs), 171
    chemical structures of, 182
    fatigue data, 182
    flexural stress amplitude vs. cycles to
    failure
    Solvay Torlon® PAI plastics, 185, 186
    lubricated wear resistance
    of Solvay Torlon® 4301, 189
    monomers, 171
    polymer units of, 183, 184
    Several Solvay Torlon® PAI Plastics
    wear factor and coefficient of friction,
    188
    Solvay Torlon® 4301, 189
    tension/tension stress amplitude vs.
    cycles to failure
    Solvay Torlon® 7130, 185
    Solvay Torlon® PAI plastics, 185
    tribology data, 182
    wear characteristics against metals
    Solvay Torlon® 4301 PAI, 190
    wear characteristics of Solvay Torlon®
    PAI Bearing Grades, 189
    wear factor and coefficient of friction
    Lubricated Environment of Several
    Solvay Torlon® PAI Resins, 189
    wear resistance vs. pressure, 186
    Solvay Torlon® 4301, 188
    Solvay Torlon® PAI plastics, 187
    Polyamide plastics. See Nylons
    Polyarylamide (PAA), 225
    fatigue data, 233
    flexural stress amplitude vs. cycles to
    failure
    Solvay Ixef® 1022, 259
    PAMXD6, chemical structure of, 259
    tribological properties
    of Solvay Ixef® PAA Plastics, 260
    tribology data, 233
    Polyaryl ether ketones (PAEK), 317
    carbon fiber–reinforced Solvay
    KetaSpire® PEEK resins, 320
    coefficient of friction vs. PV factor
    Victrex WG PAEK resins, 327
    comparative tribological data
    Victrex plc Victrex PEEK plastics,
    323
    counterface temperature vs. PV
    Victrex WG PAEK resins, 328
    dynamic coefficient of friction vs.
    temperature
    Greene, Tweed & Co. Arlon® 1260,
    322
    Victrex plc Victrex® 450FC30, 322
    Evonik Industries VESTAKEEP®
    Ultimate PEEK resin, 321
    flexural stress amplitude vs. cycles to
    failure
    SABIC Innovative Plastics PEEK
    plastics, 319
    friction coefficients and wear rates, 323
    glass fiber–reinforced Solvay KetaSpire®
    PEEK, 321
    polyetheretherketone, 317
    fatigue data, 317
    tribology data, 317
    polymers, structures of, 318
    Solvay KetaSpire® PEEK resins, 320
    stress amplitude vs. cycles to failure
    Victrex® PEEK plastics, 319
    tensile fatigue
    Solvay AvaSpire® AV-621 GF30
    BG20, 327
    Solvay AvaSpire® PAEK resins, 326
    Unfilled Victrex® PEK and PEKEKK
    Resins, 327
    tribological properties
    RTP Company RTP 2200 AR 15 TFE
    15 vs. 1018 C Steel, 325
    RTP Company RTP 2200 LF TFE 15
    vs. 1018 C Steel, 324
    RTP Company RTP 2200 LF TFE 20
    vs. 1018 C Steel, 324
    RTP Company RTP 2205 TFE 15 vs.
    1018 C Steel, 325
    RTP Company RTP 2285 TFE 15 vs.
    1018 C Steel, 326
    RTP Company RTP 2299 X 57352 A
    vs. 1018 C Steel, 326
    Victrex plc Victrex® TL-60, 323
    wear factor vs. PV
    Victrex WG PAEK resins, 328
    wear factor vs. temperature
    Greene, Tweed & Co. Arlon® 1260,
    322
    wear resistance data
    Plastic Against Steel (1018 C), 324
    Polybenzimidazole (PBI), 336
    coefficient of friction data
    of Celazole TL-60, 343
    countersurface temperature data
    of Celazole TL-60, 343
    friction and wear
    Celanese Fortron® PPS on Steel, 340
    structure of, 342
    tribology data, 342
    wear factor data
    Celazole TL-60 PBI, 343
    Polybutadiene, 69
    Polybutylene terephthalate (PBT), 125,
    135, 193
    BASF Ultradur polybutylene
    terephthalate polyester
    friction vs. pressure, dynamic
    coefficient of, 149
    wear rate vs. pressure, 149
    Celanese Celanex® grades, wear
    behavior of, 151
    Celanese Celanex® PBT plastics friction
    taber abrasion of coefficient, 152
    chemical structure of, 142
    Evonik Industries Vestodur® 2000
    sliding coefficient of friction vs.
    pressure, 150
    fatigue data, 142
    flexural fatigue strength, 144
    flexural stress amplitude vs. cycles to
    failure
    Celanese Celanex® 2300 GV/30, 143
    DuPont Engineering Polymers
    Crastin® PBT plastics, 144
    of DuPont Engineering Polymers
    Crastin® PBT plastics, 143
    DuPont Engineering Polymers
    Crastin® SK645FR, 144
    SABIC Innovative Plastics LNP™
    Stat-Kon® WC-4036, 145
    SABIC Innovative Plastics LNP
    Thermocomp®—fiber-reinforced
    PBT plastics, 145
    several Celanese Celanex® PBT
    plastics, 143
    friction vs. pressure loading, dynamic
    coefficient of350 Subject Index
    Celanese Celanex® 2500, 150
    friction vs. sliding speed, dynamic
    coefficient of
    Celanese Celanex® 2500, 150
    kinetic friction, coefficient of, 151
    Mitsubishi Engineering-Plastics
    NOVADURAN® PBT Resins
    flexural fatigue of, 148
    PV limit value, 152
    specific wear rate of, 151
    performance properties, 135
    stress amplitude vs. cycles to failure
    of DSM Arnite®—unreinforced
    PBT, 142
    tensile stress amplitude vs. cycles to
    failure
    SABIC Innovative Plastics Valox®, 146
    SABIC Innovative Plastics Valox®
    310, 145
    SABIC Innovative Plastics Valox®
    325, 148
    SABIC Innovative Plastics Valox®
    420, 146
    SABIC Innovative Plastics Valox®
    430, 147
    SABIC Innovative Plastics Valox®
    736, 147
    SABIC Innovative Plastics Valox®
    412E, 146
    SABIC Innovative Plastics Valox®
    732E, 147
    SABIC Innovative Plastics Valox®
    HV7075, 148
    tribology data, 149
    Polycarbonate (PC) polyester, 76, 125
    chemical structure of, 125
    monomers, 125
    coefficient of friction vs. temperature
    SABIC Innovative Plastics Lexan®
    101R, 136
    dynamic coefficient of friction vs.
    time, 136
    fatigue crack propagation rate
    dependence
    on cyclic frequency and stress
    intensity factor, 133
    on cyclic frequency and
    temperature, 133
    fatigue data, 126
    fatigue resistance, in compression
    molecular weight effect, 134
    fatigue resistance, in flexure
    molecular weight effect, 134
    fatigue resistance, in torsion
    molecular weight effect, 134
    Mitsubishi Engineering-Plastics
    Corporation Iupilon®/Novarex®
    PC resin, PV values for, 137
    RTP Company RTP 300 AR 10 TFE 10
    vs. 1018 C Steel, 140
    RTP Company RTP 300 AR 10 vs. 1018
    C Steel, 140
    RTP Company RTP 300 TFE 10 SI 2 vs.
    1018 C Steel, 140
    RTP Company RTP 300 TFE 5 vs. 1018
    C Steel, 138
    RTP Company RTP 300 TFE 10 vs.
    1018 C Steel, 139
    RTP Company RTP 300 TFE 15 vs.
    1018 C Steel, 139
    RTP Company RTP 300 TFE 20 vs.
    1018 C Steel, 140
    RTP Company RTP 302 TFE 15 vs.
    1018 C Steel, 141
    RTP Company RTP 305 TFE 15 vs.
    1018 C Steel, 141
    RTP Company RTP 382 TFE 15 vs.
    1018 C Steel, 141
    RTP Company RTP 385 TFE 15 vs.
    1018 C Steel, 141
    RTP Company RTP 300 TFE 5 vs. RTP
    300 TFE 5, 139
    RTP Company RTP 300 TFE 10 vs.
    RTP 300 TFE 10, 139
    RTP Company RTP 300 TFE 15 vs.
    RTP 300 TFE 10, 139
    RTP Company RTP 382 TFE 15 vs.
    RTP 382 TFE 15, 141
    SABIC Innovative Plastics Lexan®, 142
    SABIC Innovative Plastics Lexan® ML
    6339R carbon particle
    long-term S–N data, 133
    short-term S–N data, 133
    samples, fatigue properties
    Mitsubishi Engineering-Plastics
    Corporation Iupilon®/Novarex®
    PC resin, 135
    temperature influence on fatigue resistance
    Mitsubishi Engineering-Plastics
    Corporation Iupilon®/Novarex®
    PC resin, 135
    tensile stress amplitude vs. cycles to
    failure
    SABIC Innovative Plastics Lexan®
    101, 126
    SABIC Innovative Plastics Lexan®
    121, 126
    SABIC Innovative Plastics Lexan®
    141, 127
    SABIC Innovative Plastics Lexan®
    191, 127
    SABIC Innovative Plastics Lexan®
    500, 128
    SABIC Innovative Plastics Lexan®
    920, 128
    SABIC Innovative Plastics Lexan®
    925, 129
    SABIC Innovative Plastics Lexan®
    940, 129
    SABIC Innovative Plastics Lexan®
    945, 129
    SABIC Innovative Plastics Lexan®
    955, 130
    SABIC Innovative Plastics Lexan®
    EM1210, 130
    SABIC Innovative Plastics Lexan®
    EM2212, 130
    SABIC Innovative Plastics Lexan®
    EM3110, 131
    SABIC Innovative Plastics Lexan®
    HF1110, 131
    SABIC Innovative Plastics Lexan®
    HF1130, 131
    SABIC Innovative Plastics Lexan®
    HF1140, 132
    SABIC Innovative Plastics Lexan®
    LS1, 132
    SABIC Innovative Plastics Lexan®
    OQ1030, 132
    SABIC Innovative Plastics Lexan®
    143R, 127
    SABIC Innovative Plastics Lexan®
    915R, 128
    tribology data, 135
    wear rate vs. sliding distance, 136
    wear resistance data determination
    by Thrust Washer Test Against 1018
    C steel for RTP 300 Series, 138
    by Thrust Washer Test Per ASTM
    D3702 for RTP 300 Series, 137
    Polychlorotrifluoroethylene (PCTFE), 303
    chemical structure of, 309
    fatigue crack growth, 310
    fatigue data, 310
    Polycyclohexylene-dimethylene
    terephthalate (PCT), 159
    chemical structure, 159
    fatigue cycles to failure vs. stress
    in tension for DR and EF series, 160
    fatigue data, 159
    tensile stress amplitude vs. cycles to
    failure
    SABIC Innovative Plastics Valox®
    fire-retardant PCT plastics, 160
    Polydispersity, 52
    Polyester plastics, 125
    Polyether block amides (PEBA), 284
    Polyetheretherketone (PEEK), 197
    Polyetherimide (PEI), 171
    amine reaction, with anhydride, 172
    biphenol diamine PMDA
    polyetherimide, chemical
    structure of, 172
    BPADA-DDS polyetherimide sulfone,
    chemical structure of, 172
    BPADA monomer, chemical structure
    of, 173
    BPADA-MPD polyetherimide, chemical
    structure of, 173
    BPADA-PMDA-MPD
    copolyetherimide, chemical
    structure of, 173
    BPADA-PPD polyetherimide, chemical
    structure of, 172
    fatigue cycles to failure vs. stress
    SABIC Innovative Plastics reinforced
    LNP polyetherimide imide
    compounds, 174
    Polybutylene terephthalate (PBT) (cont.)Subject Index 351
    fatigue data, 171
    monomer, chemical structure of, 173
    SABIC Innovative Plastics Ultem®
    polyetherimide compounds, 174
    tensile stress amplitude vs. cycles
    SABIC Innovative Plastics PEI
    plastics, 179
    SABIC Innovative Plastics Ultem®,
    175, 176
    SABIC Innovative Plastics Ultem®
    1000, 174
    SABIC Innovative Plastics Ultem®
    1010, 175
    SABIC Innovative Plastics Ultem®
    2100, 175
    SABIC Innovative Plastics Ultem®
    2300, 176
    SABIC Innovative Plastics Ultem®
    2400, 176
    SABIC Innovative Plastics Ultem®
    3452, 177
    SABIC Innovative Plastics Ultem®
    AR9000 series PEI plastics, 178
    SABIC Innovative Plastics Ultem®
    CRS5000 series PEI plastics,
    178
    SABIC Innovative Plastics Ultem®
    series PEI plastics, 179
    SABIC Innovative Plastics Ultem®
    4000 series PEI plastics, 177
    SABIC Innovative Plastics Ultem®
    9000 series PEI plastics, 177
    tribological properties
    RTP Company RTP 2100 AR 15 TFE
    15 vs. 1018 C Steel, 181
    RTP Company RTP 4205 TFE 15,
    180
    RTP Company RTP 4285 TFE 15,
    180
    RTP Company RTP 4299 X 64425 vs.
    1018 C Steel, 181
    RTP Company RTP 4299 X 71927 vs.
    1018 C Steel, 180
    several SABIC Innovative Plastics
    Ultem® Series PEI plastics, 181
    tribology data, 171
    Polyether plastics
    acetals-polyoxymethylene
    homopolymer, 87
    fatigue data, 87
    tribology data, 87
    polyoxymethylene copolymer
    (POM-Co), 87
    polyphenylene ether, 95
    fatigue data, 111
    polyphenylene oxide (PPO), 95
    fatigue data, 111
    Polyethersulfone (PES), 317
    BASF Ultrason® E 2010, Wohler
    diagram, 330
    fatigue data, 320
    flexural stress amplitude vs. cycles to
    failure
    BASF Ultrason® E PES plastics, 330
    SABIC Innovative Plastics
    Thermocomp® PES plastics, 329
    Solvay Advanced Polymers, 329
    friction coefficient and wear intensity,
    331
    structure of, 328
    taber abrasion loss vs. glass fiber content
    Solvay Radel® A PES plastics, 331
    tribology data, 320
    for Mitsui Chemicals, Inc., 331
    Polyethylene (PE), 45, 261
    classifications of, 261
    cycles to failure vs. deflection in flexure,
    264
    dynamic coefficient of friction vs.
    pressure
    of LyondellBasell Industries
    polyolefins Lupolen® PE, 265
    fatigue crack propagation (FCP) rate vs.
    stress intensity range in tension,
    264
    fatigue crack propagation vs. stress
    intensity factor, 265
    fatigue cycles to failure vs. stress in
    flexure
    high-density polyethylene, 263
    Ipiranga Petrochem Hostalen GM
    501OT2, 263
    fatigue data, 262
    homopolymers, 263
    impact copolymers, 264
    jet abrasion volume vs. jet velocity
    of LyondellBasell Industries
    polyolefins Lupolen® PE, 266
    random copolymers, 264
    tribology data, 262
    wear rate vs. mean pressure
    by pin-on-disk of LyondellBasell
    Industries polyolefins Lupolen®,
    266
    Polyethylene chlorotrifluoroethylene, 293
    chemical structure of, 299
    tribology data, 294
    Polyethylene crystal structure, graphical
    diagram of, 262
    Polyethylene terephthalate (PET), 45, 125,
    149, 193
    chemical structure of, 152
    DuPont Engineering Polymers Rynite®
    PET Plastics, 155
    fatigue data, 152
    flexural stress amplitude vs. cycles to
    failure
    DuPont Engineering Polymers
    Rynite® FR400 series
    flame-retardant, 155
    tribology data, 152
    Polyethylene tetrafluoroethylene, 296
    Asahi Glass Fluon® C-55AP/ C-55AXP
    ETFE resins
    dynamic friction coefficient vs.
    PV, 302
    Asahi Glass Fluon® C-55AP/C-55AXP
    ETFE resins
    wear constant vs. PV, 302
    Asahi Glass Fluon® C-88AP/C-88AXP
    ETFE resins
    dynamic friction coefficient vs.
    PV, 303
    wear constant vs. PV, 303
    Asahi Glass Fluon® C-88AXMP ETFE
    resin
    dynamic friction coefficient vs.
    PV, 304
    wear constant vs. PV, 304
    chemical structure, 299
    Chemours Tefzel® HT-2004
    frictional behavior of, 301
    Glass Fiber–Reinforced ETFE
    Bearing Wear Rate, 305
    static coefficient of friction, 304
    fatigue data, 299
    flexural stress amplitude vs. cycles to
    failure
    Chemours Tefzel® ETFE
    plastics, 300
    fiber-reinforced ETFE plastics, 300
    MIT folding endurance, at room
    temperature, 301
    tribology data, 299
    Polyethylene types, graphical depictions
    of, 262
    Polyformaldehyde, 87
    Polyimide (PI), 182
    chemical structure, 191
    DuPont Engineering Polymers Vespel®
    PI plastics
    wear and friction properties, 195
    dynamic coefficient of friction vs.
    temperature
    DuPont Engineering Polymers
    Vespel® SP PI plastics, 192
    fatigue data, 186
    fatigue resistance vs. temperature to
    failure
    DuPont Engineering Polymers
    Vespel® SP PI plastics, 191
    lubricated friction test, 191, 192
    maximum PV limits
    Unlubricated DuPont Engineering
    Polymers Vespel® PI Plastics, 195
    monomers, chemical structures of, 190
    pressure vs. velocity limit
    DuPont Engineering Polymers
    Vespel® SP21, 193
    tribology data, 186
    wear factor vs. roughness of
    unlubricated countermaterial
    hardness, 194
    wear factor vs. unlubricated
    countermaterial hardness, 194
    wear factor vs. velocity limit at
    DuPont Engineering Polymers
    Vespel® SP PI plastics, 193
    wear rate vs. PV, 194352 Subject Index
    Polyimide plastics, 171
    Polyketones. See Polyaryl ether ketones
    (PAEK)
    Polyketones or polyaryl ether ketones
    (PAEK), 317
    Polymerization, 45
    addition, 45
    chain initiation, 45
    chain propagation, 45
    chain termination, 45
    condensation, 45, 46
    Polymers, intramolecular attractions, 51
    chain entanglement, 52
    hydrogen bonding, 51
    van der Waals forces, 52
    Polymer’s molecular weight, 52
    crystalline and amorphous regions, 54
    crystalline vs. amorphous, 54
    fatigue life
    heat treatment on, 55
    of PTFE, 55
    hypothetical molecular weight
    distribution plot, 52
    polystyrene on fatigue life, 53
    polyvinyl chloride on fatigue crack
    propagation, 54
    thermosets vs. thermoplastics, 53
    Polyolefins, 261
    monomers, chemical structures
    of, 261
    polymers, structures of, 262
    Polyolefin thermoplastic elastomer (TPO),
    287
    tribological properties
    RTP Company RTP 2800-35A SI 2
    vs. 1018 C Steel, 288
    RTP Company RTP 2800-35A TFE
    20 vs. 1018 C Steel, 288
    RTP Company RTP 2800-60A TFE
    20 vs. 1018 C Steel, 288
    RTP Company RTP 2800-60A vs.
    1018 C Steel, 288
    tribological properties of
    RTP Company RTP 2800-40D TFE
    20 vs. 1018 C Steel, 287
    RTP Company RTP 2800-40D vs.
    1018 C Steel, 287
    tribology data, 287
    Polyoxymethylene copolymer (POM-Co),
    87
    acetal copolymer, chemical structure
    of, 95
    Celanese Hostaform® Grades
    Wear and Dynamic Coefficient of
    Friction, 111
    chemical structure of, 95
    dynamic coefficient of friction vs.
    bearing pressure
    Celanese Celcon® POM-Co, 101
    dynamic coefficient of friction vs.
    bearing speed
    Celanese Celcon® POM-Co, 102
    fatigue data, 95
    flexural stress amplitude vs. cycles to
    failure
    for BASF Ultraform® POM-Co
    plastics, 99
    Celanese Celcon® POM-Co plastics, 96
    for Celanese Hostaform® C 9021
    POM-Co plastics, 98
    Hz for several Celanese Hostaform®
    POM-Co plastics, 97
    fluctuating stress amplitude vs. cycles
    to failure
    for Celanese Hostaform® C 9021, 96
    Mitsubishi Engineering-Plastics
    Corporation Iupital® POM-Co
    Plastics
    coefficient of static friction, 106
    Mitsubishi Engineering-Plastics
    Corporation Iupital® POM-Co
    plastics, 105
    coefficient of kinetic friction and
    surface pressure, 104
    coefficient of kinetic friction and
    velocity, 104
    specific wear volume vs. velocity, 106
    Mitsubishi Engineering-Plastics
    Corporation Iupital® POM-Co
    Plastics coefficient of static
    friction
    specific wear volume, 107
    radial wear vs. load on unlubricated
    journal
    Celanese Celcon® POM-Co, 101
    RTP Company ESD 800 Static
    Dissipative vs. 1018 C Steel
    tribological properties of, 107
    RTP Company RTP 800 Base Resin vs.
    1018 C Steel
    tribological properties of, 107
    RTP Company RTP 800 SI 2 vs. 1018
    C Steel
    tribological properties of, 107
    RTP Company RTP 800 TFE 10 SI 2
    wear resistance data of, 111
    RTP Company RTP 800 TFE 5 vs. 1018
    C Steel
    tribological properties of, 108
    RTP Company RTP 800 TFE 10 vs.
    1018 C Steel
    tribological properties of, 108
    RTP 800 Series Acetal (POM)
    Compounds
    wear resistance data of, 108, 110
    sliding friction coefficient vs. roughness
    sliding steel disk, 103
    sliding steel disk
    wear rate vs. roughness, 103
    tensile fatigue strength vs. cycles to
    failure
    Mitsubishi Engineering-Plastics
    Corporation Iupital® POM-Co
    plastics, 100
    tensile stress amplitude vs. cycles to
    failure
    for Celanese Hostaform® C 9021, 97
    torsional stress amplitude vs. cycles to
    failure
    for Celanese Hostaform® C 9021,
    98, 99
    tribology data, 95
    unlubricated Celanese Celcon®
    POM-Co, PV curve, 102
    Unlubricated Standard Celanese
    Celcon® Acetal Copolymer
    Against Other Materials
    dynamic coefficient of
    friction, 106
    Polyphenylene ether (PPE), 76, 95
    fatigue data, 111
    flexural stress amplitude vs. cycles to
    failure
    SABIC Innovative Plastics LNP™
    Thermocomp™ ZF-1006, 112
    polyphenylene oxides
    chemical structure of, 111
    tensile stress amplitude vs. cycles to
    failure
    SABIC Innovative Plastics Noryl®
    731, 116
    SABIC Innovative Plastics Noryl®
    EM6101, 117
    SABIC Innovative Plastics Noryl®
    EM7100, 118
    SABIC Innovative Plastics Noryl®
    EM6100F, 117
    SABIC Innovative Plastics Noryl®
    EM7304F, 118
    SABIC Innovative Plastics Noryl®
    FN150X, 119
    SABIC Innovative Plastics Noryl®
    FN215X, 119
    SABIC Innovative Plastics Noryl®
    GFN1, 120
    SABIC Innovative Plastics Noryl®
    GFN2, 120
    SABIC Innovative Plastics Noryl®
    GFN3, 121
    SABIC Innovative Plastics Noryl®
    GTX954, 112
    SABIC Innovative Plastics Noryl®
    HH195—PPE/PS plastic, 116
    SABIC Innovative Plastics Noryl®
    HS1000X, 121
    SABIC Innovative Plastics Noryl®
    HS2000X, 122
    SABIC Innovative Plastics Noryl®
    IGN320, 122
    SABIC Innovative Plastics Noryl®
    PPX615, 113
    SABIC Innovative Plastics Noryl®
    PPX630, 113
    SABIC Innovative Plastics Noryl®
    PPX640, 114
    SABIC Innovative Plastics Noryl®
    PPX7110, 114
    SABIC Innovative Plastics Noryl®
    PPX7112, 115Subject Index 353
    SABIC Innovative Plastics Noryl®
    PPX7115, 115
    Polyphenylene oxide (PPO), 95
    fatigue data, 111
    Polyphenylene sulfide (PPS)
    coefficient of abrasion vs. PV value
    Toray Resin Company Torelina® A504
    plastics, 338
    coefficient of friction
    Solvay Advanced Polymers Ryton®
    R-4, 340
    fatigue data, 330
    flexural stress amplitude vs. cycles to
    failure
    Celanese Fortron® PPS plastics, 332
    SABIC Innovative Plastics Supec®
    G401, 335
    SABIC Innovative Plastics Supec®
    G620, 336
    friction and wear
    Celanese Fortron® PPS on Steel, 340
    high-molecular-weight (HMW)
    linear, 325
    stress amplitude vs. cycles to failure
    Toray Resin Company Torelina® PPS
    plastics, 336, 337
    structure of, 332
    taber abrasion of
    Solvay Advanced Polymers Ryton®
    Plastics, 340
    tensile fatigue S – N curve
    Celanese Fortron® 1140A1, 333
    Celanese Fortron® 6165A4, 334
    tensile strength retained vs. cycles to
    failure
    Solvay Advanced Polymers Ryton®
    A-200 PPS, 334
    Solvay Advanced Polymers Ryton®
    R-4, 335
    Solvay Advanced Polymers Ryton®
    R-7, 335
    Solvay Advanced Polymers Ryton®
    R-4 02XT, 334
    tensile stress amplitude vs. cycles to
    failure
    Celanese Fortron® PPS plastics, 332,
    333
    tribology data, 330
    tribology properties of
    Toray Resin Company Torelina® PPS
    Resins, 338
    wear resistance data determination
    Thrust Washer Test Per ASTM
    D3702 of RTP 1300 Series, 340
    Polyphthalamide (PPA), 224
    chemical structures of blocks, 255
    fatigue data, 224
    flexural stress amplitude vs. cycles to
    failure
    EMS-Grivory Grivory®, 257
    EMS-Grivory Grivory® fiberreinforced PAA, 256
    EMS-Grivory Grivory® HTV-5H1, 257
    EMS-Grivory Grivory® HTV-6H1, 258
    SABIC Innovative Plastics PPA
    plastics, 258
    Solvay Amodel® A-1145 HS, 255
    Solvay Amodel® glass fiber, 256
    high-performance polyamide, 223
    tribology data, 225
    wear resistance data
    Thrust Washer Test Per ASTM
    D3702 Against Steel (1018 C),
    259
    Polyphthalate carbonate (PPC) polyester,
    159
    chemical structure of, 160
    fatigue data, 161
    flexural stress amplitude vs. cycles to
    failure, 162
    DuPont Engineering Polymers
    Crastin® injection molding PBT/
    ASA alloy plastics, 162
    tensile stress amplitude vs. cycles to
    failure
    glass fiber–reinforced SABIC
    Innovative Plastics Valox® PET/
    PBT alloy plastics, 169
    SABIC Innovative Plastics Enduran®
    PET/PBT alloy plastics, 168
    SABIC Innovative Plastics Lexan®
    4501, 161
    SABIC Innovative Plastics Lexan®
    4704, 162
    SABIC Innovative Plastics Lexan®
    4701R, 161
    SABIC Innovative Plastics Valox®
    368, 163
    SABIC Innovative Plastics Valox®
    508, 163
    SABIC Innovative Plastics Valox®
    3706, 164
    SABIC Innovative Plastics Valox®
    PET/PBT alloy plastics, 168
    SABIC Innovative Plastics Xenoy®,
    166
    SABIC Innovative Plastics Xenoy®
    1102, 164
    SABIC Innovative Plastics Xenoy®
    1103, 165
    SABIC Innovative Plastics Xenoy®
    5770, 167
    SABIC Innovative Plastics Xenoy®
    1402B, 165
    SABIC Innovative Plastics Xenoy®
    1403B, 165
    SABIC Innovative Plastics Xenoy®
    CL101, 162
    SABIC Innovative Plastics Xenoy®
    1760E, 166
    SABIC Innovative Plastics Xenoy®
    K4630, 164
    SABIC Innovative Plastics Xenoy®
    PET/PC alloy plastics, 169
    SABIC Innovative Plastics Xenoy®
    X5300WX, 168
    SABIC Innovative Plastics
    Xenoy® 52xx series PBT/PC
    alloys, 166
    SABIC Innovative Plastics Xenoy®
    5xxx series PBT/PC alloys, 167
    Polypropylene
    applications, 266
    fatigue data, 266
    flexural stress amplitude vs. cycles to
    failure
    Celanese Celstran® glass fiber, 268
    LyondellBasell Industries polyolefins
    Hostacom® PP plastics, 267
    SABIC Innovative Plastics
    Thermocomp® MF-1006, 267
    SABIC Innovative Plastics Verton®,
    268
    homopolymers, 263
    impact copolymers, 264
    manufacturers/trade names, 265
    maximum strain vs. life for different
    frequencies, 269
    maximum stress vs. life for different
    frequencies, 269
    random copolymers, 264
    types of, 263
    Polystyrene (PS), 65
    Polysulfone (PSU), 330
    BASF Ultrason® S PSU Plastics
    friction coefficient and wear intensity,
    342
    fatigue crack propagation rate vs.
    temperature, 342
    fatigue data, 333
    flexural stress amplitude vs. cycles to
    failure
    BASF Ultrason® PSU plastics, 341
    SABIC Innovative Plastics
    Thermocomp® PSU plastics, 341
    structure of, 341
    tribology data, 333
    Polytetrafluoroethylene (PTFE), 27, 54,
    157
    ball-and-stick three-dimensional
    representation, 293
    chemical structure of, 292
    Chemours Teflon® PTFE
    dynamic coefficient of friction vs.
    sliding speed, 297
    Chemours Teflon® PTFE Filled
    Compounds
    PV and wear performance, 298
    coefficient of friction vs. load, 298
    Daikin PTFE
    wear rate vs. bronze content, 297
    wear rate vs. glass content, 296
    dynamic coefficient of friction
    Various Fluon Grades, 298
    dynamic coefficient of friction vs.
    temperature, 295
    fatigue data, 293
    fatigue life of crystallinity levels, 295
    fatigue testing, 10354 Subject Index
    flexural stress amplitude vs. cycles to
    failure, 293, 294
    fluoroplastics, melting point ranges of, 292
    homopolymer, 291
    MIT Folding Endurance Test
    Daikin Modified PTFE and Standard
    PTFE Compounds, 295
    monomers, structures of, 292
    polymer, 291
    temperature rise vs. fatigue cycles, 294
    three-dimensional representation, 292
    tribology data, 293
    wear factor vs. temperature of generic
    PTFE, 296
    Polytetramethylene glycol (PTMG), 284
    Polyvinyl chloride (PVC), 45, 72
    Polyvinyl fluoride (PVF), 311
    DuPont Tedlar® PVF film, exposure to
    steam, 313
    DuPont Tedlar® PVF films, flex life, 314
    fatigue crack propagation (FCP) rate vs.
    stress intensity, 314
    fatigue data, 313
    structure of, 313
    Polyvinylidene fluoride (PVDF), 310
    Arkema Kynar® and Kynar Flex® PVDF
    Fluoropolymers
    taber abrasion properties of, 312
    tribology properties of, 313
    chemical structure of, 310
    fatigue crack propagation vs. stress
    intensity factor, 312
    fatigue data, 310
    tensile stress amplitude vs. cycles to
    failure
    Solvay Solexis Solef® 1010, 311
    Solvay Solexis Solef® PVDF, 311
    tribology data, 310
    POM-Co. See Polyoxymethylene
    copolymer (POM-Co)
    PPC polyester. See Polyphthalate
    carbonate (PPC) polyester
    PPS. See Polyphenylene sulfide (PPS)
    PS. See Polystyrene (PS)
    PSU. See Polysulfone (PSU)
    PVDF. See Polyvinylidene fluoride
    (PVDF)
    PVF. See Polyvinyl fluoride (PVF)
    R
    Random copolymers, 264
    Rigid polyvinyl chloride, 268
    fatigue crack propagation
    polyvinyl chloride, molecular weight
    of, 273
    fatigue crack propagation rate vs. stress
    intensity factor, 273, 274
    fatigue cycles to failure vs. stress in
    tension, 273
    fatigue data, 270
    flexural stress amplitude vs. cycles to
    failure
    PolyOne Corporation Geon™
    Fiberloc™ PVC plastics, 272
    Rolling contact wear, 31
    S
    SABIC Innovative Plastics
    Enduran, 142
    SABIC Innovative Plastics Noryl®, 111
    Sliding wear processes
    abrasive wear, 30
    adhesive wear, 30
    fretting wear, 30
    surface fatigue wear, 30
    Solar cells, 312
    Solvay Solexis Hyflon® MFA, 302
    Standard Test Method for Film Hardness
    by Pencil Test, 39
    Stereoisomerism, 50
    Steric hindrance, 49
    Stress intensity factor range, 22
    Stress, types of, 1
    flexural/bending, 2–3
    illustration of, 2
    hoop, 3–4
    illustration of, 3
    instron universal testing machine
    three-point flexural/bending test, 3
    shear, 1
    illustration of, 1
    sheet fatigue-testing specimens
    illustration of, 4
    tensile/compressive, 1
    illustration of, 1
    torsional, 2
    illustration of, 2
    rods/beams, constants, 2
    Styrene, 65
    Styrene acrylonitrile, 68
    fatigue data, 68
    flexural stress amplitude vs. cycles to
    failure, 68
    tensile stress amplitude vs. cycles to
    failure
    for SABIC Innovative Plastics Geloy®
    CR7010, 69
    for SABIC Innovative Plastics Geloy®
    CR7510, 70
    for SABIC Innovative Plastics Geloy®
    CR7520, 70
    for SABIC Innovative Plastics Geloy®
    CR7020 ASA, 69
    Styrene maleic anhydride (SMA), 84
    production of, 84
    Styrenic blends, 76
    fatigue data, 77
    tensile stress amplitude vs. cycles to
    failure
    for SABIC Innovative Plastics
    Cycolac® FR15—flame-retardant
    ABS, 77
    for SABIC Innovative Plastics
    Cycolac® FR23—flame-retardant
    ABS, 77
    for SABIC Innovative Plastics
    Cycolac® KJB—medium-impact
    ABS, 78
    for SABIC Innovative Plastics
    Cycolac® LDA—ABS, 78
    tribology data, 78
    Styrenic block copolymer (SBC), 84
    “microscopic” structure of, 84
    Styrenic block copolymer (SBS), 289
    Styrenic plastics, 78
    acrylonitrile–styrene–acrylate
    (ASA), 65
    fatigue data, for ASA plastics, 67
    flexural stress amplitude vs. cycles to
    failure, 67
    high-impact polystyrene (HIPS)
    stress amplitude vs. cycles to
    failure, 66
    vs. number of fatigue cycles, 66
    high-impact polystyrene, structure of, 66
    methacrylate acrylonitrile butadiene
    styrene (MABS) copolymer, 78
    polystyrene
    effect of molecular weight, 67
    polystyrene (PS), 65
    fatigue data, 65
    polystyrene, fatigue crack propagation
    rates, 68
    styrene maleic anhydride (SMA), 81
    production of, 84
    properties of, 81
    styrenic block copolymer (SBC), 84
    “microscopic” structure of, 84
    Taber Abrasion SABIC Innovative
    Plastics Cycoloy® PC ABS
    Plastics, 83
    tensile stress amplitude vs. cycles to
    failure
    for SABIC Innovative Plastics
    Cycolac® MG47, 79
    for SABIC Innovative Plastics
    Cycolac® MGABS01 ABS, 80
    for SABIC Innovative Plastics
    Cycolac® MG38F, 79
    for SABIC Innovative Plastics
    Cycolac® MGX53GP, 80
    for SABIC Innovative Plastics
    Cycolac® X11, 80
    for SABIC Innovative Plastics
    Cycolac® X37, 81
    for SABIC Innovative Plastics
    Cycoloy® C1100, 81
    for SABIC Innovative Plastics Geloy®
    XP4025, 82
    for SABIC Innovative Plastics Geloy®
    XP4034, 83
    for SABIC Innovative Plastics Geloy®
    XP4020R, 82
    Syndiotactic polypropene, 51
    T
    Taber Shear/Scratch Tester, 41
    Terephthalic acid (TPA), 223
    Polytetrafluoroethylene (PTFE) (cont.)Subject Index 355
    Thermoplastic copolyester elastomers
    (TPE-E/COPE), 280
    coefficient of friction
    DuPont Hytrel® Thermoplastic
    Copolyester Elastomers, 285
    DuPont Hytrel® TPE-E or COPE, 282
    taber abrasion
    of Riteflex® thermoplastic polyester
    elastomers, 286
    Ticona Riteflex® thermoplastic
    copolyester elastomers,
    molecular structure of, 283
    tribology data, 284
    Thermoplastic elastomers (TPEs), 279
    molded/extruded on standard plasticsprocessing, 279
    physical and chemical properties, 279
    polyurethane, 279
    styrenic block copolymer (SBS), 289
    thermoplastic polyurethane (TPU), 279
    aromatic and aliphatic varieties, 280
    molecular structure of, 279
    polycaprolactone, 280
    polyester, 279
    polyester-based, 280
    polyether, 280
    polyether-based, 280
    tribology data, 280
    vulcanized elastomeric alloys (EA), 289
    Thermoplastic polyesters, 125
    Thermoplastic polyether block amide
    elastomers, 284
    DeMattia flexural fatigue, 286
    fatigue data, 286
    taber abrasion
    of Arkema Pebax® Polyether Block
    Amide Elastomers, 286
    Evonik Industries Vestamid®
    E Polyether Block Amide
    Elastomers, 287
    tribology data, 286
    Thermoplastic polyimide (TPI), 186
    Thermoplastic polyurethane (TPU), 279
    abrasion loss of BASF Elastollan®, 282
    abrasion loss of BASF Elastollan® B
    grades polyether-polyurethane
    thermoplastic elastomers, 281
    abrasion loss of BASF Elastollan® C
    grades polyether-polyurethane
    thermoplastic elastomers, 281
    abrasion loss of BASF Elastollan® 500
    grades polyether-polyurethane
    thermoplastic elastomers, 282
    abrasion loss of BASF Elastollan® 1100
    grades polyether-polyurethane
    thermoplastic elastomers, 281
    abrasion loss of BASF Elastollan® 600
    grades polyether-polyurethane
    transparent thermoplastic
    elastomers, 282
    aromatic and aliphatic varieties, 280
    elastoblend special grades polyetherpolyurethane thermoplastic
    elastomers, 282
    molecular structure of, 279
    polycaprolactone, 280
    polyester-based, 279, 280
    polyether-based, 280
    tribology data, 280
    tribology properties of
    Covestro Texin®, 283
    desmopan TPU thermoplastic
    elastomers, 283
    Thermoplastic UHMWPE, 266
    Thrust washer test, 36
    Ticona Riteflex® thermoplastic copolyester
    elastomers, molecular structure
    of, 283
    Tortuous path effect, 61
    Total true strain, 17
    TPE-E/COPE. See Thermoplastic
    copolyester elastomers
    (TPE-E/COPE)
    TPU. See Thermoplastic polyurethane
    (TPU)
    Trade names, 329
    Tribology testing, 34
    erosion tests, 38
    falling abrasive/erosion test, 38
    slurry erosion tests, 38
    falling abrasive abrasion/erosion tester,
    39
    hardness pencil holder, 40
    hardness testing, 39
    laboratory hardness measures, 40
    pencil hardness test, 39
    shore/rockwell hardness, 40
    linear reciprocating abrasion
    testing, 36
    load frame, 35
    pin-on-disk abrasion testing, 36, 37
    pin-on-disk wear track, 37
    reciprocating tribometer equipment, 38
    shore hardness instrument, 40
    standard tribology tests, 41
    static coefficient of friction, 35
    taber abraser, 37, 38
    taber shear/scratch tester, 41
    testing for friction, 34–35
    thrust washer, 35
    test equipment, 36
    wear/abrasion tests, 35
    thrust washer abrasion testing,
    35–36
    U
    Ultrahigh-molecular-weight polyethylene,
    266
    dynamic coefficient of friction vs.
    pressure at velocity
    Celanese GUR® UHMWPE, 270
    dynamic coefficient of friction vs.
    sliding speed
    Celanese GUR® UHMWPE, 271
    fatigue crack propagation vs. stress
    intensity factor
    UHMWPE plastics, 270
    fatigue data, 267
    permissible unlubricated bearing load
    vs. sliding speed
    Celanese GUR® UHMWPE, 271
    PV load limit vs. sliding speed
    Celanese GUR® UHMWPE, 272
    tribology data, 268
    Ultralow-density polyethylene (ULDPE),
    261
    Unsaturation, 48
    polymer polarities, qualitative ranking
    of, 48
    polymer structures, 49
    V
    Very-low-density polyethylene (VLDPE),
    261
    Vespel products, 32
    Vinyl benzene, 65
    Vinylidene fluoride, 310
    Von Mises equivalent stress formula, 4
    Vulcanized elastomeric alloys
    (EA), 289
    W
    Water pump impellers, 111
    Wear, 29
    classification of, 29
    processes, 30
    transition temperature, 32
    Wear-resistant additives, 41
    aromatic polyamide fiber, 43
    ASTM/ISO tribology-related standards,
    42
    carbon fibers, 43
    glass fiber reinforcement, 43
    glass fibers, 43
    graphite’s unique chemical lattice
    structure, 41
    MoS
    2, 41
    perfluoropolyether (PFPE) synthetic
    oil, 41
    PTFE, 41
    silicone/polysiloxane fluid, 41
    silicone resin, 43
    X
    XPS. See Extruded polystyrene
    (XPS)
    Y
    Young’s modulus, 17

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